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Stellite Cobalt-Based Alloy Forgings

Stellite is a type of cobalt alloy. Cobalt technology includes significant deposits of nickel, chromium and tungsten, as well as smaller deposits of molybdenum, niobium, tantalum, titanium and lanthanum. Outside of the nickel alloy, the steel does not lose its ductility as a function of residual elements in the matrix, but rather as a structure surrounded by a single, dense, semi-cubic austenitic matrix with few carbides in the matrix. These alloys have very high mechanical strength, high thermal stability, high thermal stability in excess of 980 °C, and consequently excellent thermal stability.

 

Stellite forgings are positioned as key wear-resistant/erosion-resistant/high-temperature components under extreme working conditions. They replace conventional stainless steel and tool steel in high-end manufacturing fields such as high-temperature and high-pressure valves, aerospace engines, nuclear power plants, and petrochemical plants, significantly extending equipment lifespan and reducing maintenance costs.

Stellite Cobalt-Based Alloy Forgings

 

 

Core Positioning and Overview of Stellite Cobalt-Based Alloy Forged Products

Stellite is a type of cobalt alloy. Cobalt technology includes significant deposits of nickel, chromium and tungsten, as well as smaller deposits of molybdenum, niobium, tantalum, titanium and lanthanum. Outside of the nickel alloy, the steel does not lose its ductility as a function of residual elements in the matrix, but rather as a structure surrounded by a single, dense, semi-cubic austenitic matrix with few carbides in the matrix. These alloys have very high mechanical strength, high thermal stability, high thermal stability in excess of 980 °C, and consequently excellent thermal stability.

 

Stellite forgings are positioned as key wear-resistant/erosion-resistant/high-temperature components under extreme working conditions. They replace conventional stainless steel and tool steel in high-end manufacturing fields such as high-temperature and high-pressure valves, aerospace engines, nuclear power plants, and petrochemical plants, significantly extending equipment lifespan and reducing maintenance costs.

 

Applicable Operating Conditions and Industries for Stellite Cobalt-Based Alloy Forgings

 

  • High wear resistance environment: High hardness and significant carbide strengthening effect can resist abrasive wear, sliding wear and erosion wear.
  • High-temperature working environment: Cr element forms a dense Cr₂O₃ protective film in the high-temperature oxygen-rich environment, effectively preventing oxidation and corrosion. The alloy can still maintain a hardness of over 30 HRC at 600℃, while most tool steels will significantly soften above 500℃.
  • Strong corrosive medium environment: It has strong corrosion resistance in solutions such as nitric acid and acetic acid. Mo element improves the corrosion resistance in aqueous solutions.

 

Applicable Industries

 

Industry Typical Operating Conditions Product Forms
Aerospace Jet Engine Combustion Chambers, High-Temperature Gas Passages, Bearings, Valve Seats Turbine Blades, Combustion Chamber Liners, Nozzle Guide Vanes, Fasteners, Exhaust Valve Seats
Oil & Gas High-Temperature/High-Pressure Valves, Drilling Equipment, Cutters, Wear-Resistant Components Valve Balls, Valve Seats, Pump Bodies, Drill Bits, Flow Control Components
Chemical/Petrochemical Highly Corrosive Media, Acidic/Alkaline Environments, High-Temperature/High-Pressure Reactions Reactors, Pump Bodies, Valves, Pipe Wear Liners, Flue Gas Desulfurization (FGD) Scrubber Towers
Power Generation/Nuclear Power Nuclear Valves, Steam Turbines, High-Temperature Gas Turbine Components Steam Valves, Guide Vanes, High-Temperature Fasteners, Bearings, Bushings
Steel & Heavy Industry Molten Metal Contact, Hot Working Tooling Guide Rollers, Hot Forging Dies, Stamping Dies, Extrusion Dies, Thermocouple Protection Tubes
Automotive Industry Exhaust Systems, Turbochargers Exhaust System Components, Turbochargers, Fuel Injectors

 

 

Stellite Cobalt-Based Alloy Forgings: Product Features and Advantages

 

  1. Excellent wear resistance and anti-adhesion performance: The high carbon content and carbide precipitation give the alloy excellent metal-on-metal anti-adhesion performance, especially suitable for sliding contact conditions without lubrication.
  2. Outstanding high-temperature performance: The alloy’s strength and hardness can remain above 800°C, and still maintain a hardness of over 30 HRC at 600°C, significantly superior to traditional tool steel.
  3. Excellent corrosion and oxidation resistance: The high chromium content (28% – 32%) forms a dense Cr₂O₃ oxide film, resistant to sulfuric acid, nitric acid and chloride environments, with outstanding anti-corrosion and anti-corrosion erosion capabilities.
  4. Good resistance to thermal fatigue and thermal shock: The carbide has good thermal stability, with its strength decreasing slowly as the temperature rises, suitable for frequent thermal cycling conditions.
  5. Improvement of comprehensive performance through deformation/forging processing: Compared to casting or welding, forged Stellite (such as 6B) has more excellent mechanical integrity and machinability, maintaining ductility, and is suitable for parts subjected to impact loads and cyclic conditions.

 

 

Physical and Mechanical Properties Table for Stellite Cobalt-Based Alloy Forgings

 

Stellite 6B (Typical Forging Alloy)

Property Typical Value Test Standard
Density 8.42 g/cm³ ASTM B311
Melting Range 1320–1395℃ ASTM E1268
Thermal Conductivity(100℃) 13.0 W/m·K ASTM E1225
Coefficient of Thermal Expansion(20-400℃) 13.2 µm/m·℃ ASTM E228
Modulus of Elasticity(20℃) 205 GPa ASTM E111
Hardness 33–43 HRC (Annealed) / 45 HRC (Aged) ASTM E18
Tensile Strength 1050–1200 MPa ASTM E8
Yield Strength(0.2%) 550–700 MPa ASTM E8
Elongation 10–20% ASTM E8

 

 

Stellite 25 (High-Temperature Structural Forgings)

Property Typical Value
Density 9.13 g/cm³
Melting Range 1330–1410℃
Thermal Conductivity(100℃) 12.6 W/m·K
Coefficient of Thermal Expansion(20-400℃) 13.1 µm/m·℃
Modulus of Elasticity(20℃) 210 GPa
Hardness 25–32 HRC (Annealed) / 33–40 HRC (Aged)
Tensile Strength 930–1100 MPa
Yield Strength(0.2%) 430–550 MPa
Elongation 25–35%

 

Overview of the Stellite Alloy Product Series

 

  • General-Purpose Wear-Resistant Type (High Hardness, Wear Resistance)
Grade Hardness(HRC) Typical Applications
Stellite 1 47–53 (As-cast) Valve seating surfaces, cutting tools, drill bits, pump bushings, bearings
Stellite 3 55–60 High carbon content and high hardness; seals, valve seats
Stellite 6/6B 38–44 Most widely used grade: valve seating surfaces, pump components, turbine blades, bearings
Stellite 12 44–49 Higher carbon and tungsten content; superior wear resistance compared to Grade 6; suitable for high-wear conditions such as mining machinery, extrusion dies, choke valves, and control valves
Stellite 190 60+ Boron-containing, ultra-high wear resistance; concrete cutting tools, crusher rollers

 

  • Corrosion-Resistant Type (High Cr/Mo, Chemical Corrosion Resistance)
Grade Hardness

(HRC)

Typical Applications
Stellite 21 25–30 Low-Carbon, High-Molybdenum: Medical Implants, Chemical Pump Seals, Nuclear Valves, High-Temperature/High-Impact Components
Stellite 31(X-40) 35–40 High-Nickel, Heat- and Corrosion-Resistant: Gas Turbine Blades, Marine Environment Components
Stellite 712 45–50 Resistant to Sulfuric and Nitric Acids: Petrochemical Reactors, Acid Pumps

 

  • High-Temperature Specialized Grade (Oxidation-Resistant, Thermal Fatigue-Resistant)
Grade Maximum Service Temperature Typical Applications
Stellite 4 1000℃ Aero-engine blades and combustion chamber liners
Stellite 25(L-605) 1100℃ Nuclear power valves, high-temperature fasteners, and bearings; offering balanced mechanical properties combined with exceptional creep resistance and fatigue life
Stellite 156 1150℃ Ta/Nb-bearing alloys; rocket nozzles and turbine guide vanes

 

  • Special-Purpose / Medical Grade
Grade characteristic Applications
Stellite 21 Low Carbon, High Molybdenum Biocompatible Artificial Joints, Dental Implants
Stellite 27 Optimized Ni/Cr Ratio Orthopedic Screws, Cardiovascular Devices
Stellite F Low Co (30%); Cost-Optimized Parts (Alternative to Grade 6)
Stellite 306 High Silicon (2.5%) Glass Molds, Molten Metal Contact Components

 

 

Stellite Cobalt-Based Alloy: Product Specifications and Supply Forms

 

Product Form Typical Size Range Description
Bars Φ8mm–Φ355mm Includes round bars and hexagonal bars; Cold-drawn round bars: Φ4–20mm; Hot-rolled round bars: Φ20–50mm
Plates Thickness: 0.5–60mm; Width: 650–2000mm Hot-rolled heavy plates (4.5–36mm); Cold-rolled sheets/strips (0.8–4.5mm)
Tubes Seamless tubes: Φ3×0.5mm–Φ114×6mm; Large-diameter welded pipes: up to Φ830–2500mm Customizable upon request
Forgings Forged bars: Φ45–200mm; Rings, discs, flanges, bushings | Customizable according to customer drawings

 

 

Supply Condition & Surface Finish

 

  • Delivery Condition: Forged, Cast, Annealed, Solution-Treated, Age-Hardened
  • Surface Finish: Black (As-Forged/Cast), Turned, Ground (Precision Peeled/Polished), Pickled
  • Machining Precision: Precision-machined finished parts can be supplied in strict accordance with blueprint tolerance requirements, making them suitable for applications with stringent tolerance demands in the aerospace, power generation, and chemical processing sectors.

 

Stellite Cobalt-Based Alloy Manufacturing Process and Processing Techniques

 

Step 1: Vacuum Induction Melting (VIM)

The initial melting is carried out in a vacuum environment, effectively removing gases and low-melting-point impurities, ensuring the purity of the alloy.

 

Step 2: Electroslag Remelting (ESR) (optional, for high-end products)

Further purify the alloy, eliminate segregation, and refine the grains to make the structure more uniform and dense.

 

Step 3: Forging/Hot Working Forming

The hot working temperature range is 1200 – 980℃, with an appropriate forging temperature of about 1170℃, to reduce the formation of intergranular carbides and control the grain size. Through radial forging, free forging or rolling, form rods/plates/blanking pieces. The forged products have better toughness and more uniform and consistent properties compared to the cast state.

 

Step 4: Solution Treatment + Aging Heat Treatment

Solution treatment: at a high temperature of about 1150℃, allowing the primary carbides and some MC-type carbides to dissolve into the solution. Aging treatment: carried out at 870 – 980℃, promoting the uniform re-crystallization of carbides and optimizing hardness and wear resistance. Some low-carbon alloys (such as Stellite 25) mainly achieve strengthening through solution treatment rather than aging carbide precipitation strengthening.

 

Step 5: Precision Machining

Using hard alloy or ceramic tools, with low cutting speed and high feed rate for machining.

 

Step 6: Quality Control and Third-Party Testing

Ultrasonic testing (UT), penetrant testing (PT), hardness testing, mechanical property testing, chemical composition analysis; support third-party authoritative institutions for testing and issuing reports.

 

Step 7: Packaging and Shipping

Cut to the required lengths, surface treatment (grinding/finishing/acid washing) after packaging and shipping.

 

 

Stellite Cobalt-Based Alloy: Quality Assurance and Company Advantages

 

Standard Type Applicable Standard Corresponding Grade
ASTM ASTM F75 (Cast CoCrMo) Stellite 21
AMS AMS 5385、AMS 5387、AMS 5894、AMS 5537 Stellite 1/21/6B/25
UNS R30001(Stellite 1)、R30006(Stellite 6)、R30016(Stellite 6B)、R30605(Stellite 25) Respective Corresponding Grades
SAE SAE J775、SAE J467B Stellite 6、Stellite 6B

 

 

Factory inspection items:

Chemical composition analysis (spectroscopy / wet analysis)

Mechanical property tests at room temperature / high temperature

Hardness tests (Rockwell / Brinell / Vickers)

Metallographic structure examination

Ultrasonic flaw detection (internal defect detection)

Dimensional accuracy inspection

Verification by third-party testing institutions (such as SGS, BV, etc.)

Material certification: We can provide EN 10204 3.1 (factory certification) or 3.2 (third-party certification) certificates, depending on customer requirements.

 

 

Company Advantages

 

  • Full-process autonomous production capability: From VIM vacuum melting to precision processing, all are autonomously controlled, and the quality is traceable.
  • Rich forging and rolling process experience: After years of research and practice, an advanced Stellite alloy forging and rolling process has been formed. The product density, strength, wear resistance, service life and other performance are all superior to those of powder metallurgy and precision casting products.
  • Full range of grades: It can produce all series of cobalt-based alloys such as Stellite 1, 4, 6, 6B, 12, 20, 21, 25, 31, 100, etc.
  • Customization capability: Various forgings, rings, flanges and precision processing components can be customized according to customer drawings.
  • Comprehensive international standard certifications: Compliant with ASTM, AMS, UNS and other international standards.

 

 

Frequently Asked Questions

 

  • Q1: Can Stellite cobalt-based alloys be welded or heat-treated?

A: They can be welded, but the process parameters need to be strictly controlled. Typically, TIG, plasma transfer arc (PTA), or oxyacetylene welding is used. Preheat at 200–400°C, strictly control the interlayer temperature, and cool slowly after welding to prevent cracking.

Regarding heat treatment:

Strain relief annealing: For grades that are not suitable for solution aging (such as Stellite 1), stress relief can be achieved by holding at 600–650°C for 2–4 hours, cooling to below 300°C in the furnace, and then removing from the furnace to avoid heating above 750°C.

Solution + aging treatment (cast alloys): 1150°C solution to dissolve carbides, 870–980°C aging to re-uniformly precipitate carbides and optimize the performance distribution.

Aging hardening alloys (such as Stellite 25): Hardness can be increased to 33–40 HRC through aging treatment.

 

  • Q2: How to choose Stellite 1, 6 and 12?

A: Select based on the working conditions:

High impact/hardness priority: Choose Stellite 6 (38–44 HRC), with a moderate hardness and good toughness, good weldability, and suitable for welding onto carbon steel, alloy steel and stainless steel substrates, suitable for most general valve applications.

High wear resistance without severe impact: Choose Stellite 1 (47–53 HRC) or Stellite 12 (44–49 HRC). Higher carbon and tungsten content produce more carbides and higher hardness. The 1st grade has the highest hardness but is relatively brittle, while the 12th grade is second. Suitable for high wear throttle valves, frequently cycled control valves, and severe erosion conditions.

High-temperature nuclear valves/strong impact/medical: Choose Stellite 21 (25–30 HRC), low-molybdenum substitution for tungsten, providing better ductility and anti-thermal shock performance, reducing the sensitivity to intermetallic compound precipitation.

High-temperature (>1000°C) structural components: Choose Stellite 25, excellent creep resistance and oxidation resistance, maximum use temperature 1100°C.

 

  • Q3: Can your company provide material certification?

A: We can provide EN 10204 3.1 (factory certification) or 3.2 (third-party certification) certificates, as well as test reports from third-party authoritative testing institutions (such as SGS, BV, etc.). The certification content includes chemical composition analysis, mechanical property tests, and non-destructive testing reports, etc. Specific content can be customized according to customer requirements.

 

  • Q4: What are the differences between Stellite forged parts and cast parts?

A: Cast parts have complex shapes and strong adaptability, carbides naturally precipitate, and the cost is relatively low, but there may be casting defects such as pores and segregation, and lower toughness. Forged parts (such as Stellite 6B) are densified through hot processing, with a more uniform structure, eliminating casting defects, and having higher mechanical integrity and ductility (10–20% elongation), especially suitable for parts subjected to impact loads and cyclic conditions. However, some high-carbon grades (such as Stellite 3) are extremely difficult to hot process and are usually not processed by the forging method.

 

  • Q5: How difficult is the processing of Stellite alloys? What are the countermeasures?

A: The processing is difficult. The cutting machining index is approximately 0.4 (forged 45 steel is 1). The main challenges include: high hardness causing rapid tool wear, carbides causing abrasive wear, strong tendency of processing hardening, and accumulation of cutting heat. Countermeasures: Use hard alloy or ceramic tools; adopt low cutting speed and high feed rate strategies; maintain the rigidity of the process system; fully use cutting fluid; grinding as the main finishing method. It is recommended to perform rough processing in the solution state (softened state), and only perform fine grinding after aging hardening.

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